Safety Data Sheet

 SECTION 1. Identification of the substance/mixture and of the company/undertaking	

 1.1. Product identifier	
 Code:	AM1220.64 	
 Product name	PLAST PF GIALLO MEDIO 	

 1.2. Relevant identified uses of the substance or mixture and uses advised against	
 Intended use	plastisol per stampa serigrafica	

 1.3. Details of the supplier of the safety data sheet	
 Name	AMEX S.R.L 	
 Full address	VIALE DELLO SPORT 12 	
 District and Country	22070 APPIANO GENTILE (CO) 	
 	IT 	
 	Tel. 031931923 	
 	Fax 031933789 	
 e-mail address of the competent person		
 responsible for the Safety Data Sheet	melissa@amexsrl.it 	

 1.4. Emergency telephone number	
 For urgent inquiries refer to	031931923                                                                                   Poison Control Center - Ospedale Niguarda - Milano - tel. 02/66101029 	

 SECTION 2. Hazards identification	

2.1. Classification of the substance or mixture

The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements).

 Hazard classification and indication:	--	

2.2. Label elements

 Hazard pictograms:	--	

 Signal words:	--	

 Hazard statements:	--	

 Precautionary statements:	--	

2.3. Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.

 SECTION 3. Composition/information on ingredients	

 3.2. Mixtures	

The product does not contain substances classified as being hazardous to human health or the environment pursuant to the provisions Regulation (EC) 1272/2008 (CLP) (and subsequent amendments and supplements) in such quantities as to require the statement.

 SECTION 4. First aid measures	

4.1. Description of first aid measures

Not specifically necessary. Observance of good industrial hygiene is recommended.

4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

 SECTION 5. Firefighting measures	

5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

 SECTION 6. Accidental release measures	

6.1. Personal precautions, protective equipment and emergency procedures

Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in emergency procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

 SECTION 7. Handling and storage	

7.1. Precautions for safe handling

Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use.

7.2. Conditions for safe storage, including any incompatibilities

Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

 SECTION 8. Exposure controls/personal protection	

 8.1. Control parameters	

Regulatory references:

 ESP	España	Límites de exposición profesional para agentes químicos en España 2021	
 FRA	France	Valeurs limites d'exposition professionnelle aux agents chimiques en France. ED 984 - INRS	
 POL	Polska	Rozporządzenie ministra rozwoju, pracy i technologii  z dnia 18 lutego 2021 r. Zmieniające rozporządzenie w sprawie najwyższych dopuszczalnych stężeń i natężeń czynników szkodliwych  dla zdrowia w środowisku pracy	
 GBR	United Kingdom	EH40/2005 Workplace exposure limits (Fourth Edition 2020)	

 CALCIUM CARBONATE	
 Threshold Limit Value	
 Type	Country	TWA/8h		STEL/15min		Remarks / Observations		
 		mg/m3	ppm	mg/m3	ppm			
 VLA	ESP	  10						
 NDS/NDSCh	POL	  10						
 WEL	GBR	   4						

 CALCIUM CARBONATE	
 Threshold Limit Value	
 Type	Country	TWA/8h		STEL/15min		Remarks / Observations		
 		mg/m3	ppm	mg/m3	ppm			
 VLEP	FRA	  10						
 NDS/NDSCh	POL	  10				INHAL		
 Predicted no-effect concentration - PNEC				
 Normal value of STP microorganisms	100	mg/l		
 Health - Derived no-effect level - DNEL / DMEL	
 	Effects on consumers				Effects on workers				
 Route of exposure	Acute local	Acute systemic	Chronic local	Chronic systemic	Acute local	Acute systemic	Chronic local	Chronic systemic	
 Oral		6,1 mg/kg bw/d		6,1 mg/kg bw/d					
 Inhalation				10 mg/m3				10 mg/m3	

Legend:

(C) = CEILING   ;   INHAL = Inhalable Fraction   ;   RESP = Respirable Fraction   ;   THORA = Thoracic Fraction.

VND = hazard identified but no DNEL/PNEC available   ;   NEA = no exposure expected   ;   NPI = no hazard identified   ;   LOW = low hazard   ;   MED = medium hazard   ;   HIGH = high hazard.

 8.2. Exposure controls	

Comply with the safety measures usually applied when handling chemical substances.

Comply with the safety measures usually applied when handling chemical substances.

HAND PROTECTION
None required.

SKIN PROTECTION
None required.

EYE PROTECTION
None required.

RESPIRATORY PROTECTION
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. Use a mask with a type A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387).
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

 SECTION 9. Physical and chemical properties	

 9.1. Information on basic physical and chemical properties	

 Properties	Value	Information	
 Appearance	paste		
 Colour	brown		
 Odour	mild		
 Odour threshold	not available		
 Melting point / freezing point	not available		
 Initial boiling point	not available		
 Flammability	not available		
 Lower explosive limit	not available		
 Upper explosive limit	not available		
 Flash point	> 100 °C		
 Auto-ignition temperature	not available		
 Decomposition temperature	not available		
 pH	not available		
 Kinematic viscosity	not available		
 Solubility	insoluble in water		
 Partition coefficient: n-octanol/water	not available		
 Vapour pressure	not available		
 Density and/or relative density	1,33		
 Relative vapour density	not available		

 9.2. Other information	

 9.2.1. Information with regard to physical hazard classes	

 Information not available	

 9.2.2. Other safety characteristics	

 Total solids (250°C / 482°F)	99,00 %		
 VOC (Directive 2010/75/EU)	0,22 %    -    2,95    g/litre		
 VOC (volatile carbon)	0,32 %    -    4,23    g/litre		

 SECTION 10. Stability and reactivity	

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

CALCIUM CARBONATE

CALCIUM CARBONATE: decomposes at temperatures above 800°C.

CALCIUM CARBONATE

Decomposes at temperatures above 800°C/1472°F.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid

None in particular. However the usual precautions used for chemical products should be respected.

10.5. Incompatible materials

CALCIUM CARBONATE

CALCIUM CARBONATE: acids.

CALCIUM CARBONATE

Incompatible with: acids.

10.6. Hazardous decomposition products

CALCIUM CARBONATE

CALCIUM CARBONATE: calcium oxides, carbon oxides.

CALCIUM CARBONATE

May develop: calcium oxides,carbon oxides.

 SECTION 11. Toxicological information	

According to currently available data, this product has not yet produced health damages. Anyway, it must be handled according to good industrial practices.
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available
ACUTE TOXICITY ATE (Inhalation) of the mixture:	Not classified (no significant component)	
 ATE (Oral) of the mixture:	Not classified (no significant component)	
 ATE (Dermal) of the mixture:	Not classified (no significant component)	

SKIN CORROSION / IRRITATION

Does not meet the classification criteria for this hazard class

SERIOUS EYE DAMAGE / IRRITATION

Does not meet the classification criteria for this hazard class

RESPIRATORY OR SKIN SENSITISATION

Does not meet the classification criteria for this hazard class

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY

Does not meet the classification criteria for this hazard class

REPRODUCTIVE TOXICITY

Does not meet the classification criteria for this hazard class

STOT - SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

STOT - REPEATED EXPOSURE

Does not meet the classification criteria for this hazard class

ASPIRATION HAZARD

Does not meet the classification criteria for this hazard class

11.2. Information on other hazards

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine disruptors with human health effects under evaluation.

 SECTION 12. Ecological information	

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation.

12.1. Toxicity

Information not available

12.2. Persistence and degradability

Information not available

12.3. Bioaccumulative potential

Information not available

12.4. Mobility in soil

Information not available

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

12.6. Endocrine disrupting properties

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine disruptors with environmental effects under evaluation.

12.7. Other adverse effects

Information not available

 SECTION 13. Disposal considerations	

13.1. Waste treatment methods

Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING 
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

 SECTION 14. Transport information	

The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

14.1. UN number or ID number

not applicable

14.2. UN proper shipping name

not applicable

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

not applicable

14.6. Special precautions for user

not applicable

14.7. Maritime transport in bulk according to IMO instruments

Information not relevant

 SECTION 15. Regulatory information	

 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture	

Seveso Category - Directive 2012/18/EU: None

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006

Product
 Point	40		

Contained substance

 Point	75		

Regulation (EU) 2019/1148 - on the marketing and use of explosives precursors

not applicable

Substances in Candidate List (Art. 59 REACH)

On the basis of available data, the product does not contain any SVHC in percentage ≥ than 0,1%.

Substances subject to authorisation (Annex XIV REACH)

None

Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012:

None

Substances subject to the Rotterdam Convention:

None

Substances subject to the Stockholm Convention:

None

Healthcare controls

Information not available

 15.2. Chemical safety assessment	

A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3.

 SECTION 16. Other information	

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- ATE: Acute Toxicity Estimate
- CAS: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE: Identifier in ESIS (European archive of existing substances)
- CLP: Regulation (EC) 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: Regulation (EC) 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA: Time-weighted average exposure limit
- TWA STEL: Short-term exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EC) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 2020/878 (II Annex of REACH Regulation)
4. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP)
13. Regulation (EU) 2017/776 (X Atp. CLP)
14. Regulation (EU) 2018/669 (XI Atp. CLP)
15. Regulation (EU) 2019/521 (XII Atp. CLP)
16. Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP)
17. Regulation (EU) 2019/1148
18. Delegated Regulation (UE) 2020/217 (XIV Atp. CLP)
19. Delegated Regulation (UE) 2020/1182 (XV Atp. CLP)
20. Delegated Regulation (UE) 2021/643 (XVI Atp. CLP)
21. Delegated Regulation (UE) 2021/849 (XVII Atp. CLP)
22. Delegated Regulation (UE) 2022/692 (XVIII Atp. CLP)
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- IFA GESTIS website
- ECHA website
- Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy

Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
CALCULATION METHODS FOR CLASSIFICATION
Chemical and physical hazards: Product classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for evaluation of chemical-physical properties are reported in section 9.
Health hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section 11.
Environmental hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in Section 12.

Changes to previous review:
The following sections were modified:
03 / 11 / 12.