Safety Data Sheet
According to Annex II to REACH - Regulation (EU) 2015/830

 SECTION 1. Identification of the substance/mixture and of the company/undertaking	

 1.1. Product identifier	
 Code:	AM1220.93 	
 Product name	PLAST PF ORO 	

 1.2. Relevant identified uses of the substance or mixture and uses advised against	
 Intended use	plastisol per stampa serigrafica	

 1.3. Details of the supplier of the safety data sheet	
 Name	AMEX S.R.L 	
 Full address	VIALE DELLO SPORT 12 	
 District and Country	22070 APPIANO GENTILE (CO) 	
 	IT 	
 	Tel. 031931923 	
 	Fax 031933789 	
 e-mail address of the competent person		
 responsible for the Safety Data Sheet	melissa@amexsrl.it 	

 1.4. Emergency telephone number	
 For urgent inquiries refer to	031931923                                                                                   Poison Control Center - Ospedale Niguarda - Milano - tel. 02/66101029 	

 SECTION 2. Hazards identification	

2.1. Classification of the substance or mixture

The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP).
However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data sheet with appropriate information, compliant to (EU) Regulation 2015/830.

 Hazard classification and indication:	--	

2.2. Label elements

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.

 Hazard pictograms:	--	

 Signal words:	--	

 Hazard statements:		
 EUH210	Safety data sheet available on request.	

 Precautionary statements:	--	

2.3. Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

 SECTION 3. Composition/information on ingredients	

 3.2. Mixtures	

Contains:

 Identification	x = Conc. %	Classification (EC) 1272/2008 (CLP)		
 2-METHYLPENTANE-2,4-DIOL				
 CAS   107-41-5	1 ≤ x <  3	Eye Irrit. 2 H319, Skin Irrit. 2 H315		
 EC   203-489-0				
 INDEX   603-053-00-3				
 REACH Reg.   01-2119539582-35-xxxx				

The full wording of hazard (H) phrases is given in section 16 of the sheet.

 SECTION 4. First aid measures	

4.1. Description of first aid measures

EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice.
SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again.
INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

 SECTION 5. Firefighting measures	

5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

 SECTION 6. Accidental release measures	

6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

 SECTION 7. Handling and storage	

7.1. Precautions for safe handling

Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

 SECTION 8. Exposure controls/personal protection	

 8.1. Control parameters	

Regulatory References:

 DEU	Deutschland	Technischen Regeln für Gefahrstoffe (TRGS 900) - Liste der Arbeitsplatzgrenzwerte und Kurzzeitwerte. MAK- und BAT-Werte-Liste 2020, Ständige Senatskommission zur Prüfung gesundheitsschädlicher Arbeitsstoffe, Mitteilung 56	
 ESP	España	Límites de exposición profesional para agentes químicos en España 2019	
 FRA	France	Valeurs limites d'exposition professionnelle aux agents chimiques en France. ED 984 - INRS	
 POL	Polska	Rozporządzenie Ministra Rodziny, Pracy i Polityki Społecznej z dnia 12 czerwca 2018 r. w sprawie najwyższych dopuszczalnych stężeń i natężeń czynników szkodliwych dla zdrowia w środowisku pracy	
 GBR	United Kingdom	EH40/2005 Workplace exposure limits (Fourth Edition 2020)	
 	TLV-ACGIH	ACGIH 2020	

 2-METHYLPENTANE-2,4-DIOL	
 Threshold Limit Value	
 Type	Country	TWA/8h		STEL/15min		Remarks / Observations		
 		mg/m3	ppm	mg/m3	ppm			
 MAK	DEU	  49	  10	  98	  20			
 VLA	ESP			 123	  25			
 VLEP	FRA			 125	  25			
 NDS/NDSCh	POL	  50		 100		INHAL		
 WEL	GBR	 123	  25	 123	  25			
 TLV-ACGIH			  25		  50			
 TLV-ACGIH				  10		INHAL		

Legend:

(C) = CEILING   ;   INHAL = Inhalable Fraction   ;   RESP = Respirable Fraction   ;   THORA = Thoracic Fraction.

 8.2. Exposure controls	

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice.
Personal protective equipment must be CE marked, showing that it complies with applicable standards.

HAND PROTECTION
Protect hands with category III work gloves.
The following should be considered when choosing work glove material (see standard EN 374): compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use.

SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body with soap and water after removing protective clothing.

EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).

RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

 SECTION 9. Physical and chemical properties	

 9.1. Information on basic physical and chemical properties	

 Properties	Value	Information	
 Appearance	paste		
 Colour	gold		
 Odour	mild		
 Odour threshold	not available		
 pH	not available		
 Melting point / freezing point	not available		
 Initial boiling point	not available		
 Boiling range	not available		
 Flash point	> 100 °C		
 Evaporation rate	not available		
 Flammability	not available		
 Lower inflammability limit	not available		
 Upper inflammability limit	not available		
 Lower explosive limit	not available		
 Upper explosive limit	not available		
 Vapour pressure	not available		
 Relative vapour density	not available		
 Relative density	not available		
 Solubility	insoluble in water		
 Partition coefficient: n-octanol/water	not available		
 Auto-ignition temperature	not available		
 Decomposition temperature	not available		
 Kinematic viscosity	not available		
 Explosive properties	not available		
 Oxidising properties	not available		

 9.2. Other information	

 Total solids (250°C / 482°F)	86,04 %		
 VOC (Directive 2010/75/EU) :	2,81 %		
 VOC (volatile carbon) :	1,89 %		

 SECTION 10. Stability and reactivity	

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

2-METHYLPENTANE-2,4-DIOL

Decomposes under the effect of heat.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid

None in particular. However the usual precautions used for chemical products should be respected.

2-METHYLPENTANE-2,4-DIOL

Avoid exposure to: sources of heat,naked flames.

10.5. Incompatible materials

2-METHYLPENTANE-2,4-DIOL

Incompatible with: strong acids,strong oxidants.Compatible materials: carbon steel,aluminium.

10.6. Hazardous decomposition products

Information not available

 SECTION 11. Toxicological information	

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product.

11.1. Information on toxicological effects

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

 ATE (Inhalation) of the mixture:	Not classified (no significant component)	
 ATE (Oral) of the mixture:	Not classified (no significant component)	
 ATE (Dermal) of the mixture:	Not classified (no significant component)	

2-METHYLPENTANE-2,4-DIOL
LC50 (Inhalation): 

 LD50 (Oral):	> 3500 mg/kg	
 LD50 (Dermal):	> 5000 mg/kg	
 LC50 (Inhalation):	> 310 mg/l/4h	

SKIN CORROSION / IRRITATION

Does not meet the classification criteria for this hazard class

SERIOUS EYE DAMAGE / IRRITATION

Does not meet the classification criteria for this hazard class

RESPIRATORY OR SKIN SENSITISATION

Does not meet the classification criteria for this hazard class

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY

Does not meet the classification criteria for this hazard class

REPRODUCTIVE TOXICITY

Does not meet the classification criteria for this hazard class

STOT - SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

STOT - REPEATED EXPOSURE

Does not meet the classification criteria for this hazard class

ASPIRATION HAZARD

Does not meet the classification criteria for this hazard class

 SECTION 12. Ecological information	

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation.

12.1. Toxicity

 2-METHYLPENTANE-2,4-DIOL			
 LC50 - for Fish		9450 mg/l/96h	
 EC50 - for Crustacea		5410 mg/l/48h	
 EC50 - for Algae / Aquatic Plants		> 420 mg/l/72h	
12.2. Persistence and degradability

 2-METHYLPENTANE-2,4-DIOL			
 Solubility in water		> 10000 mg/l 	
   Rapidly degradable
12.3. Bioaccumulative potential

 2-METHYLPENTANE-2,4-DIOL			
 Partition coefficient: n-octanol/water		< -0,14 	

12.4. Mobility in soil

Information not available

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

12.6. Other adverse effects

Information not available

 SECTION 13. Disposal considerations	

13.1. Waste treatment methods

Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING 
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

 SECTION 14. Transport information	

The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

14.1. UN number

not applicable

14.2. UN proper shipping name

not applicable

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

not applicable

14.6. Special precautions for user

not applicable

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Information not relevant

 SECTION 15. Regulatory information	

 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture	

Seveso Category - Directive 2012/18/EU: None

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006

Product
 Point	40		

Contained substance

 Point	75	2-METHYLPENTANE-2,4-DIOL REACH Reg.: 01-2119539582-35-xxxx	

 Point	75	HYDROCARBONS, C9-C11, n-ALKANES, iso-ALKANES, CYCLICS, <2% AROMATICS REACH Reg.: 01-2119463258-33-XXXX	

 Point	75	TITANIUM DIOXIDE REACH Reg.: 01-2119489379-XXXX	

 Point	75	CALCIUM CARBONATE	

 Point	75	PIGMENTO GIALLO 12 REACH Reg.: 01-2119475440-42-XXXX	

 Point	75	XYLENE (MIXTURE OF ISOMERS) REACH Reg.: 01-2119488216-32-XXXX	

Regulation (EU) 2019/1148 - on the marketing and use of explosives precursors

not applicable

Substances in Candidate List (Art. 59 REACH)

On the basis of available data, the product does not contain any SVHC in percentage ≥ than 0,1%.

Substances subject to authorisation (Annex XIV REACH)

None

Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012:

None

Substances subject to the Rotterdam Convention:

None

Substances subject to the Stockholm Convention:

None

Healthcare controls

Information not available

 15.2. Chemical safety assessment	

A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3.

 SECTION 16. Other information	

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

 Eye Irrit. 2	Eye irritation, category 2		
 Skin Irrit. 2	Skin irritation, category 2		
 H319	Causes serious eye irritation.		
 H315	Causes skin irritation.		
 EUH210	Safety data sheet available on request.		

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE: Identifier in ESIS (European archive of existing substances)
- CLP: Regulation (EC) 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: Regulation (EC) 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA: Time-weighted average exposure limit
- TWA STEL: Short-term exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EC) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP)
13. Regulation (EU) 2017/776 (X Atp. CLP)
14. Regulation (EU) 2018/669 (XI Atp. CLP)
15. Regulation (EU) 2018/1480 (XIII Atp. CLP)
16. Regulation (EU) 2019/521 (XII Atp. CLP)
17. Regulation (EU) 2019/1148
18. Regulation (EU) 2020/217 (XIV Atp. CLP)
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- IFA GESTIS website
- ECHA website
- Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy
Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
CALCULATION METHODS FOR CLASSIFICATION
Chemical and physical hazards: Product classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for evaluation of chemical-physical properties are reported in section 9.
Health hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section 11.
Environmental hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in Section 12.

Changes to previous review:
The following sections were modified:
08 / 15.