Safety Data Sheet
According to Annex II to REACH - Regulation (EU) 2020/878 and to Annex II to UK REACH

 SECTION 1. Identification of the substance/mixture and of the company/undertaking	

 1.1. Product identifier	
 Code:	AM100046 	
 Product name	SCREEN-CHEM FILLER WB BLU 	

 1.2. Relevant identified uses of the substance or mixture and uses advised against	
 Intended use	ausiliare per stampa serigrafica	

 1.3. Details of the supplier of the safety data sheet	
 Name	AMEX S.R.L 	
 Full address	VIALE DELLO SPORT 12 	
 District and Country	22070 APPIANO GENTILE (CO) 	
 	IT 	
 	Tel. 031931923 	
 	Fax 031933789 	
 e-mail address of the competent person		
 responsible for the Safety Data Sheet	melissa@amexsrl.it 	

 1.4. Emergency telephone number	
 For urgent inquiries refer to	031931923                                                                                   Poison Control Center - Ospedale Niguarda - Milano - tel. 02/66101029 	

 SECTION 2. Hazards identification	

2.1. Classification of the substance or mixture

The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2020/878.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.

Hazard classification and indication:
 Carcinogenicity, category 1B	H350	May cause cancer.	
 Eye irritation, category 2	H319	Causes serious eye irritation.	
 Skin irritation, category 2	H315	Causes skin irritation.	
 Skin sensitization, category 1	H317	May cause an allergic skin reaction.	
 Hazardous to the aquatic environment, chronic toxicity, category 2	H411	Toxic to aquatic life with long lasting effects.	

2.2. Label elements

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.

 Hazard pictograms:		

 Signal words:	Danger	

 Hazard statements:		
 H350	May cause cancer.	
 H319	Causes serious eye irritation.	
 H315	Causes skin irritation.	
 H317	May cause an allergic skin reaction.	
 H411	Toxic to aquatic life with long lasting effects.	
 	Restricted to professional users.	

 Precautionary statements:		
 P201	Obtain special instructions before use.	
 P280	Wear protective gloves/ protective clothing / eye protection / face protection.	
 P308+P313	IF exposed or concerned: Get medical advice / attention.	
 P273	Avoid release to the environment.	
 P391	Collect spillage.	
 P261	Avoid breathing dust / fume / gas / mist / vapours / spray.	
 		
 Contains:	FORMALDEHYDE	
 	Massa di reazione di: 5-cloro-2-metil-2H-isotiazol-3-one [EC no. 247-500-7]; 2-metil-2H-isotiazol-3-one [EC no. 220-239-6] (3:1)	
 	1,2-Benzoisotiazol-3(2H)-one	

2.3. Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.

 SECTION 3. Composition/information on ingredients	

 3.2. Mixtures	

Contains:

 Identification	x = Conc. %	Classification (EC) 1272/2008 (CLP)		
 FORMALDEHYDE				
 INDEX   605-001-00-5	0,7 ≤ x <  0,8	Carc. 1B H350, Muta. 2 H341, Acute Tox. 2 H330, Acute Tox. 3 H301, Acute Tox. 3 H311, Skin Corr. 1B H314, Eye Dam. 1 H318, STOT SE 3 H335, Skin Sens. 1 H317, Classification note according to Annex VI to the CLP Regulation: B, D		
 EC   200-001-8		Skin Corr. 1B H314: ≥ 25%, Skin Irrit. 2 H315: ≥ 5%, Skin Sens. 1 H317: ≥ 0,2%, Eye Dam. 1 H318: ≥ 25%, Eye Irrit. 2 H319: ≥ 5%, STOT SE 3 H335: ≥ 5%		
 CAS   50-00-0		LD50 Oral: 100 mg/kg, LD50 Dermal: 270 mg/kg, LC50 Inhalation vapours: 0,588 mg/l/4h		
 REACH Reg.   01-2119488953-20				
 Massa di reazione di: 5-cloro-2-metil-2H-isotiazol-3-one [EC no. 247-500-7]; 2-metil-2H-isotiazol-3-one [EC no. 220-239-6] (3:1)				
 INDEX   613-167-00-5	0,1 ≤ x <  0,15	Acute Tox. 2 H310, Acute Tox. 2 H330, Acute Tox. 3 H301, Skin Corr. 1B H314, Eye Dam. 1 H318, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=100, Aquatic Chronic 1 H410 M=100		
 EC   -		Skin Corr. 1B H314: ≥ 0,6%, Skin Irrit. 2 H315: ≥ 0,06%, Skin Sens. 1 H317: ≥ 0,0015%, Eye Dam. 1 H318: ≥ 0,6%, Eye Irrit. 2 H319: ≥ 0,06%		
 CAS   55965-84-9		LD50 Oral: 66 mg/kg, LD50 Dermal: >141 mg/kg, LC50 Inhalation vapours: 1,98 mg/l/1h		
 1,2-Benzoisotiazol-3(2H)-one				
 INDEX   613-088-00-6	0 ≤ x <  0,05	Acute Tox. 2 H330, Acute Tox. 4 H302, Eye Dam. 1 H318, Skin Irrit. 2 H315, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=1		
 EC   220-120-9		Skin Sens. 1 H317: ≥ 0,05%		
 CAS   2634-33-5		LD50 Oral: 1193 mg/kg, STA Inhalation vapours: 0,501 mg/l, STA Inhalation mists/powders: 0,051 mg/l		

The full wording of hazard (H) phrases is given in section 16 of the sheet.

 SECTION 4. First aid measures	

4.1. Description of first aid measures

EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops breathing, administer artificial respiration. Take suitable precautions for rescue workers.

4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

 SECTION 5. Firefighting measures	

5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

 SECTION 6. Accidental release measures	

6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

 SECTION 7. Handling and storage	

7.1. Precautions for safe handling

Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

 SECTION 8. Exposure controls/personal protection	

 8.1. Control parameters	

Regulatory References:

 DEU	Deutschland	Technischen Regeln für Gefahrstoffe (TRGS 900) - Liste der Arbeitsplatzgrenzwerte und Kurzzeitwerte. MAK- und BAT-Werte-Liste 2020, Ständige Senatskommission zur Prüfung gesundheitsschädlicher Arbeitsstoffe, Mitteilung 56	
 ESP	España	Límites de exposición profesional para agentes químicos en España 2021	
 FRA	France	Valeurs limites d'exposition professionnelle aux agents chimiques en France. ED 984 - INRS	
 ITA	Italia	Decreto Legislativo 9 Aprile 2008, n.81	
 PRT	Portugal	Decreto-Lei n.º 1/2021 de 6 de janeiro, valores-limite de exposição profissional indicativos para os agentes químicos. Decreto-Lei n.º 35/2020 de 13 de julho, proteção dos trabalhadores contra os riscos ligados à exposição durante o trabalho a agentes cancerígenos ou mutagénicos	
 POL	Polska	Rozporządzenie ministra rozwoju, pracy i technologii  z dnia 18 lutego 2021 r. Zmieniające rozporządzenie w sprawie najwyższych dopuszczalnych stężeń i natężeń czynników szkodliwych  dla zdrowia w środowisku pracy	
 GBR	United Kingdom	EH40/2005 Workplace exposure limits (Fourth Edition 2020)	
 EU	OEL EU	Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU) 2019/983; Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive 91/322/EEC.	
 	TLV-ACGIH	ACGIH 2022	

 FORMALDEHYDE	
 Threshold Limit Value	
 Type	Country	TWA/8h		STEL/15min		Remarks / Observations		
 		mg/m3	ppm	mg/m3	ppm			
 AGW	DEU	0,37	 0,3	0,74	 0,6			
 VLA	ESP	0,37	 0,3	0,74	 0,6			
 VLEP	FRA	0,37	 0,3	0,74	 0,6			
 VLEP	ITA	0,37	 0,3	0,74	 0,6			
 VLE	PRT	0,37	 0,3	0,74	 0,6			
 NDS/NDSCh	POL	0,37		0,74		SKIN		
 WEL	GBR	 2,5	   2	 2,5	   2			
 OEL	EU	0,37	 0,3	0,74	 0,6			
 TLV-ACGIH			 0,1		 0,3			
 Predicted no-effect concentration - PNEC				
 Normal value in fresh water	47	mg/l		
 Normal value in marine water	47	mg/l		
 Normal value for fresh water sediment	2,44	mg/kg		
 Normal value for marine water sediment	2,44	mg/kg		
 Normal value for water, intermittent release	4,7	mg/l		
 Normal value of STP microorganisms	0,19	mg/l		
 Normal value for the terrestrial compartment	0,21	mg/kg		
 Health - Derived no-effect level - DNEL / DMEL	
 	Effects on consumers				Effects on workers				
 Route of exposure	Acute local	Acute systemic	Chronic local	Chronic systemic	Acute local	Acute systemic	Chronic local	Chronic systemic	
 Oral				4.1 mg/kg/d					
 Inhalation			0.1 mg/m3	3.2 mg/kg	0.8 mg/kg		0.4 mg/kg	9 mg/m3	
 Skin			0.012 mg/cm2	102 mg/kg/d			0.037 mg/cm2	240 mg/kg/d	

 Massa di reazione di: 5-cloro-2-metil-2H-isotiazol-3-one [EC no. 247-500-7]; 2-metil-2H-isotiazol-3-one [EC no. 220-239-6] (3:1)	
 Threshold Limit Value	
 Type	Country	TWA/8h		STEL/15min		Remarks / Observations		
 		mg/m3	ppm	mg/m3	ppm			
 OEL	EU	 0,2		 0,4				
 Predicted no-effect concentration - PNEC				
 Normal value in fresh water	3,39	mg/l		
 Normal value in marine water	3,39	mg/l		
 Normal value for fresh water sediment	0,027	mg/kg		
 Normal value for marine water sediment	0,027	mg/kg		
 Normal value of STP microorganisms	0,23	mg/l		
 Normal value for the terrestrial compartment	0,01	mg/kg		
 Health - Derived no-effect level - DNEL / DMEL	
 	Effects on consumers				Effects on workers				
 Route of exposure	Acute local	Acute systemic	Chronic local	Chronic systemic	Acute local	Acute systemic	Chronic local	Chronic systemic	
 Oral				0,09 mg/kg bw/d					
 Inhalation	0,04 mg/m3		0,02 mg/m3		0,04 mg/m3		0,02 mg/m3		

Legend:

(C) = CEILING   ;   INHAL = Inhalable Fraction   ;   RESP = Respirable Fraction   ;   THORA = Thoracic Fraction.

VND = hazard identified but no DNEL/PNEC available   ;   NEA = no exposure expected   ;   NPI = no hazard identified   ;   LOW = low hazard   ;   MED = medium hazard   ;   HIGH = high hazard.

 8.2. Exposure controls	

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice.
Personal protective equipment must be CE marked, showing that it complies with applicable standards.

Provide an emergency shower with face and eye wash station.

The product must be used inside a closed circuit, in a well-ventilated environment and with strong localised aspiration systems in place.

HAND PROTECTION
Protect hands with category III work gloves.
The following should be considered when choosing work glove material (see standard EN 374): compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use.

SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body with soap and water after removing protective clothing.

EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).

RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways.

 SECTION 9. Physical and chemical properties	

 9.1. Information on basic physical and chemical properties	

 Properties	Value	Information	
 Appearance	liquid		
 Colour	blue		
 Odour	not available		
 Melting point / freezing point	not available		
 Initial boiling point	100 °C		
 Flammability	not available		
 Lower explosive limit	1 % (v/v)		
 Upper explosive limit	5,3 % (v/v)		
 Flash point	> 60 °C		
 Auto-ignition temperature	290 °C		
 Decomposition temperature	not available		
 pH	2,7		
 Kinematic viscosity	not available		
 Solubility	not available		
 Partition coefficient: n-octanol/water	not available		
 Vapour pressure	not available		
 Density and/or relative density	1,09		
 Relative vapour density	not available		
 Particle characteristics	not applicable		

 9.2. Other information	

 9.2.1. Information with regard to physical hazard classes	

 Information not available	

 9.2.2. Other safety characteristics	

 Total solids (250°C / 482°F)	43,03 %		
 VOC (Directive 2010/75/EU)	0,77 %    -    8,39    g/litre		
 VOC (volatile carbon)	0,31 %    -    3,35    g/litre		

 SECTION 10. Stability and reactivity	

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

FORMALDEHYDE

Decomposes under the effect of heat.

Acqueous solutions are stabilised with methanol but tend to polymerise over time.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

No hazardous reactions are foreseeable in normal conditions of use and storage.

FORMALDEHYDE

Risk of explosion on contact with: nitromethane,nitrogen dioxide,hydrogen peroxide,phenoles,performic acid,nitric acid.May polymerise on contact with: strong oxidising agents,alkalis.May react dangerously with: hydrochloric acid,magnesium carbonate,sodium hydroxide,perchloric acid,aniline.Forms explosive mixtures with: air.

10.4. Conditions to avoid

None in particular. However the usual precautions used for chemical products should be respected.

FORMALDEHYDE

Avoid exposure to: light,sources of heat,naked flames.

10.5. Incompatible materials

FORMALDEHYDE

Incompatible with: acids,alkalis,ammonia,tannin,strong oxidants,phenoles,copper salts,silver,iron.

10.6. Hazardous decomposition products

FORMALDEHYDE

When heated to decomposition releases: methanol,carbon monoxide.

 SECTION 11. Toxicological information	

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product.

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

 ATE (Inhalation - vapours) of the mixture:	> 20 mg/l	
 ATE (Oral) of the mixture:	>2000 mg/kg	
 ATE (Dermal) of the mixture:	>2000 mg/kg	

FORMALDEHYDE

 LD50 (Dermal):	270 mg/kg Rabbit	
 LD50 (Oral):	100 mg/kg Rat	
 LC50 (Inhalation vapours):	0,588 mg/l/4h Rat	

Massa di reazione di: 5-cloro-2-metil-2H-isotiazol-3-one [EC no. 247-500-7]; 2-metil-2H-isotiazol-3-one [EC no. 220-239-6] (3:1)

 LD50 (Dermal):	> 141 mg/kg RATTO	
 LD50 (Oral):	66 mg/kg RATTO	
 LC50 (Inhalation vapours):	1,98 mg/l/1h RATTO	

1,2-Benzoisotiazol-3(2H)-one

 LD50 (Dermal):	> 4115 mg/kg Ratto	
 LD50 (Oral):	1193 mg/kg Ratto	

SKIN CORROSION / IRRITATION

Causes skin irritation

SERIOUS EYE DAMAGE / IRRITATION

Causes serious eye irritation

RESPIRATORY OR SKIN SENSITISATION

Sensitising for the skin

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY

May cause cancer

REPRODUCTIVE TOXICITY

Does not meet the classification criteria for this hazard class

STOT - SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

STOT - REPEATED EXPOSURE

Does not meet the classification criteria for this hazard class

ASPIRATION HAZARD

Does not meet the classification criteria for this hazard class

11.2. Information on other hazards

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine disruptors with human health effects under evaluation.

 SECTION 12. Ecological information	

This product is dangerous for the environment and is toxic for aquatic organisms. In the long term, it have negative effects on acquatic environment.
12.1. Toxicity

 Massa di reazione di: 5-cloro-2-metil-2H-isotiazol-3-one [EC no. 247-500-7]; 2-metil-2H-isotiazol-3-one [EC no. 220-239-6] (3:1)			
 LC50 - for Fish		0,0052 mg/l/96h	
 EC50 - for Crustacea		0,12 mg/l/48h DAPHNIA MAGNA	
 EC50 - for Algae / Aquatic Plants		0,048 mg/l/72h	
 Chronic NOEC for Fish		0,098 mg/l	
 Chronic NOEC for Crustacea		0,004 mg/l	
 Chronic NOEC for Algae / Aquatic Plants		0,00064 mg/l	

 1,2-Benzoisotiazol-3(2H)-one			
 EC50 - for Crustacea		3,7 mg/l/48h Daphnia magna	
 EC50 - for Algae / Aquatic Plants		0,37 mg/l/72h	
12.2. Persistence and degradability

 FORMALDEHYDE			
 Solubility in water		55000 mg/l 	
   Rapidly degradable
12.3. Bioaccumulative potential

 Massa di reazione di: 5-cloro-2-metil-2H-isotiazol-3-one [EC no. 247-500-7]; 2-metil-2H-isotiazol-3-one [EC no. 220-239-6] (3:1)			
 Partition coefficient: n-octanol/water		0,71 	
 BCF		316 	

 1,2-Benzoisotiazol-3(2H)-one			
 Partition coefficient: n-octanol/water		0,7 	
 BCF		695 	

 FORMALDEHYDE			
 Partition coefficient: n-octanol/water		0,35 	
 BCF		< 1 	

12.4. Mobility in soil

 FORMALDEHYDE			
 Partition coefficient: soil/water		1,202 	

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.

12.6. Endocrine disrupting properties

Based on the available data, the product does not contain substances listed in the main European lists of potential or suspected endocrine disruptors with environmental effects under evaluation.

12.7. Other adverse effects

Information not available

 SECTION 13. Disposal considerations	

13.1. Waste treatment methods

Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING 
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

 SECTION 14. Transport information	

The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

14.1. UN number or ID number

not applicable

14.2. UN proper shipping name

not applicable

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

not applicable

14.6. Special precautions for user

not applicable

14.7. Maritime transport in bulk according to IMO instruments

Information not relevant

 SECTION 15. Regulatory information	

 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture	

Seveso Category - Directive 2012/18/EU: E2

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006

Product
 Point	3		

Contained substance

 Point	75		

 Point	28-72	FORMALDEHYDE REACH Reg.: 01-2119488953-20	

Regulation (EU) 2019/1148 - on the marketing and use of explosives precursors

not applicable

Substances in Candidate List (Art. 59 REACH)

On the basis of available data, the product does not contain any SVHC in percentage ≥ than 0,1%.

Substances subject to authorisation (Annex XIV REACH)

None

Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012:

None

Substances subject to the Rotterdam Convention:

None

Substances subject to the Stockholm Convention:

None

Healthcare controls

Workers exposed to this health-dangerous chemical agent must undergo sanitary checks carried out in compliance with 2004/37/EC directive.

 15.2. Chemical safety assessment	

A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3.

 SECTION 16. Other information	

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

 Carc. 1B	Carcinogenicity, category 1B		
 Muta. 2	Germ cell mutagenicity, category 2		
 Acute Tox. 2	Acute toxicity, category 2		
 Acute Tox. 3	Acute toxicity, category 3		
 Acute Tox. 4	Acute toxicity, category 4		
 Skin Corr. 1B	Skin corrosion, category 1B		
 Eye Dam. 1	Serious eye damage, category 1		
 Eye Irrit. 2	Eye irritation, category 2		
 Skin Irrit. 2	Skin irritation, category 2		
 STOT SE 3	Specific target organ toxicity - single exposure, category 3		
 Skin Sens. 1	Skin sensitization, category 1		
 Aquatic Acute 1	Hazardous to the aquatic environment, acute toxicity, category 1		
 Aquatic Chronic 1	Hazardous to the aquatic environment, chronic toxicity, category 1		
 Aquatic Chronic 2	Hazardous to the aquatic environment, chronic toxicity, category 2		
 H350	May cause cancer.		
 H341	Suspected of causing genetic defects.		
 H310	Fatal in contact with skin.		
 H330	Fatal if inhaled.		
 H301	Toxic if swallowed.		
 H311	Toxic in contact with skin.		
 H302	Harmful if swallowed.		
 H314	Causes severe skin burns and eye damage.		
 H318	Causes serious eye damage.		
 H319	Causes serious eye irritation.		
 H315	Causes skin irritation.		
 H335	May cause respiratory irritation.		
 H317	May cause an allergic skin reaction.		
 H400	Very toxic to aquatic life.		
 H410	Very toxic to aquatic life with long lasting effects.		
 H411	Toxic to aquatic life with long lasting effects.		

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- ATE: Acute Toxicity Estimate
- CAS: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE: Identifier in ESIS (European archive of existing substances)
- CLP: Regulation (EC) 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: Regulation (EC) 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA: Time-weighted average exposure limit
- TWA STEL: Short-term exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EC) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 2020/878 (II Annex of REACH Regulation)
4. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP)
13. Regulation (EU) 2017/776 (X Atp. CLP)
14. Regulation (EU) 2018/669 (XI Atp. CLP)
15. Regulation (EU) 2019/521 (XII Atp. CLP)
16. Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP)
17. Regulation (EU) 2019/1148
18. Delegated Regulation (UE) 2020/217 (XIV Atp. CLP)
19. Delegated Regulation (UE) 2020/1182 (XV Atp. CLP)
20. Delegated Regulation (UE) 2021/643 (XVI Atp. CLP)
21. Delegated Regulation (UE) 2021/849 (XVII Atp. CLP)
22. Delegated Regulation (UE) 2022/692 (XVIII Atp. CLP)
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- IFA GESTIS website
- ECHA website
- Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy

Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
CALCULATION METHODS FOR CLASSIFICATION
Chemical and physical hazards: Product classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for evaluation of chemical-physical properties are reported in section 9.
Health hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section 11.
Environmental hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in Section 12.

Changes to previous review:
The following sections were modified:
02 / 03 / 04 / 06 / 07 / 08 / 09 / 10 / 11 / 12 / 13 / 15 / 16.